Ladbrokes' Champions League acca - Liverpool & Arsenal backed in 5/1 accumulator

Barcelona vs Aston Villa

Two teams with strong Champions League starts to build on meet at the Camp Nou as Barcelona host Aston Villa on Tuesday night, but despite Villa's incredible record in Europe over the last few years, our experts are tipping the hosts to maintain their frightening form.

The LaLiga frontrunners are the bookies' favourite to win the Champions League despite losing to PSG last time out, with just two defeats to their name all season, and with Villa arriving on a mini, two-game winless run, the Premier League side have it all to do against the five-time European champions.

The electric front three of Lamine Yamal, Raphinha and Anthony Gordon have already scored 32 goals between them in all competitions this term, and with 12 wins from their last 14 games, the hosts are overwhelming favourites here.

Prediction: Barcelona to win

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Manchester United vs AS Roma

With last weekend's defeat at Stamford Bridge extending Manchester United's winless run to nine games, Michael Carrick and Co return to Old Trafford under huge pressure - and we can see the problems continuing as Roma leave with all three points.

The Italians have lost just one of their 13 matches this season, and have scored a staggering 21 goals in their last six games - including three in their loss to Real Madrid - so possess firepower that United will surely struggle to contain.

The hosts haven't found the net themselves since a consolation goal in Como on Matchday 3 of the Champions League, and have only kept one clean sheet in all competitions this term, so despite United starting the day just a point behind their Serie A opponents, our experts fear for the Premier League strugglers.

Prediction: Roma to win

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Fenerbahce vs Liverpool

Arriving in Turkey off the back of a battling defeat to Arsenal, Liverpool's attention turns to their perfect Champions League start, with nine points from a possible nine placing them firmly in the top eight ahead of kick-off - and we're backing them to make it 12 from 12 with little fuss.

The Reds suffered just their second defeat of the season on Sunday in somewhat controversial circumstances, but are still yet to lose away from home under the stewardship of Andoni Iraola, and considering Fenerbahce lost 6-0 when they faced a Premier League side (Aston Villa) a few weeks ago, Liverpool should have more than enough firepower to put their hosts to the sword.

The Turkish outfit have actually only won one of their last five in all competitions, and currently find themselves sixth in the Super Lig, so taking points off a Liverpool side with seven wins from nine (including penalty shootouts) seems a very tall ask.

Prediction: Liverpool to win

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Slavia Prague vs Arsenal

Having soared back to the top of the Premier League table with a rare but hard-fought victory at Anfield, Arsenal travel to Czechia with the odds firmly in their favour, and we're tipping them to ease past Slavia Prague on Wednesday night.

The Gunners have only lost one match inside 90 minutes since April, and arrive having won 12 of their 15 matches in all competitions this term, so against a Slavia Prague side with just two wins from their last six, the English champions shouldn't have too much trouble asserting themselves at the Fortuna Arena - a ground they won 3-0 at exactly a year ago to the day.

Arsenal's last league-phase defeat in the Champions League came back in November 2024, while Slavia Prague went the entire 2025/26 UCL campaign without picking up a single win - so with history painting a clear picture, we're backing the visitors.

Prediction: Arsenal to win

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All odds and markets are correct as of the date of publication.